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90 Capsules. MSM 500mg is composed of Methylsulfonylmethane (MSM) which is an organic sulphur-compound that occurs naturally in a variety of fruits, vegetables, grains, and animals including humans. MSM is believed to be non-toxic and shows no side effects even at high dosages. Sulfur supports healthy muscles, tendons, and ligaments, and it helps maintain the integrity of articular cartilage.